Synthesis and Crystal Structure of (η2-Olefin)(N-phenyl-2,3-dicarbomethoxy-7-azabenzonorbornadiene)Fe(CO)2Complexes

Autor: Shiao‐Yu Wu, Ju-Chun Wang, Lin‐Shu Liou, Chia-Hsing Sun
Rok vydání: 1998
Předmět:
Zdroj: Journal of the Chinese Chemical Society. 45:563-567
ISSN: 0009-4536
DOI: 10.1002/jccs.199800085
Popis: The title compounds 2a-f were obtained from photochemical substitution of 1 with alkenes as stable solids in moderate yields. X-ray structure determination of 2c shows a distorted trigonal bipyramidal geometry with two cross iron-coordinated olefins. Compounds 2a-f represent a new type of (η2-monoolefin)2(R3N)Fe(CO)2.
Databáze: OpenAIRE