Standard Chemical Thermodynamic Properties of Alkene Isomer Groups
| Autor: | Catherine A. Gehrig, Robert A. Alberty |
|---|---|
| Rok vydání: | 1985 |
| Předmět: |
Alkane
chemistry.chemical_classification Vapor pressure Chemistry Enthalpy General Physics and Astronomy Thermodynamics General Chemistry Heat capacity Ideal gas Standard enthalpy of formation Gibbs free energy symbols.namesake symbols Physical chemistry Physical and Theoretical Chemistry Equilibrium constant |
| Zdroj: | Journal of Physical and Chemical Reference Data. 14:803-820 |
| ISSN: | 1529-7845 0047-2689 |
| Popis: | The chemical thermodynamic properties of alkylbenzene isomer groups from C8H10 to C9H12 in the ideal gas phase have been calculated from 298.15 to 1000 K from tables of Stull, Westrum, and Sinke. In the absence of literature data on all isomers of higher isomer groups, the properties of isomers of C10H14 to C12H18 have been calculated using Benson group values. For isomer group properties, increments per carbon atom have been calculated to show the extent to which thermodynamic properties of higher isomer groups may be obtained by linear extrapolation. Equilibrium mole fractions within isomer groups have been calculated for the ideal gas state from 298.15 to 1000 K. Values of C○P, S○, ΔfH○, and ΔfG○ are given for all species from C6H6 to C12H18 in joules for a standard state pressure of 1 bar. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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