Synthesis and optical properties of novel unsymmetrically substituted benzothiadiazole-based luminophores

Autor:	Andrey F. Asachenko, Sergey N. Osipov, Dmitry A. Lypenko, Dmitry A. Loginov, Maxim A. Topchiy, S. I. Pozin, Pavel S. Gribanov, Artem V. Dmitriev
Rok vydání:	2021
Předmět:	Core (optical fiber) 010405 organic chemistry Chemistry OLED Sequence (biology) General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences
Zdroj:	Mendeleev Communications. 31:33-35
ISSN:	0959-9436
Popis:	New unsymmetrically substituted benzothiadiazoles were synthesized from 4,7-dibromo-2,1,3-benzothiadiazole via the sequence of Pd-catalyzed Suzuki and Buchwald–Hartwig cross-coupling reactions with 4-methoxyphenylboronic acid and heterocyclic amines, respectively. Based on initially performed photophysical study as well as DFT calculation, these compounds, in particular with dibenzoazepine core, can be selected as promising scaffolds for further fine-tuning of their properties to be used in optoelectronics including OLED technologies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2ed9b96ceecbaf529346382c44c5e57d https://doi.org/10.1016/j.mencom.2021.01.009 Zobrazit plný text záznamu Full Text from ScienceDirect