Steric hindrance and molecular conformation

Autor:	S. L. Solenova, Yu. T. Struchkov, T. L. Khotsyanova
Rok vydání:	1960
Předmět:	Steric effects Crystallography chemistry.chemical_compound Chemistry Hydrochloride Molecule Space group General Chemistry Cell parameter Molecular conformation
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 9:292-299
ISSN:	1573-9171 0568-5230
Popis:	1. Goniometric measurements were carried out on polyhalobenzenes and their derivatives (15 compounds in all) having substantial steric hindrance in their molecules. 2. The unit cell parameters, the space groups, and some other crystallochemical characteristics of these crystals were determined. 3. 2,6-Diiodo-4-nitroanisole was shown to be dimorphous. 4. The coordinates of the heavy atoms were determined for two of the substances, (3,4,5-trichloroaniline hydrochloride and 1,3,5-trichloro-2-nitrobenzene), and the full structure was determined for one of the substances (2-bromo-1,3,5-trichlorobenzene). 5. From the substances studied, a selection was made of those showing the greatest promise for full structural analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c742df465a5cb3ade9542f83fe7302a https://doi.org/10.1007/bf00942906 Zobrazit plný text záznamu Full text from SpringerLink