Copper–dienamine catalysis: γ-oxyamination of α,β-unsaturated aldehydes

Autor:	Pranab K. Shyam, Won-Ji Jung, Xuan-Huong Ho, Hye-Young Jang
Rok vydání:	2014
Předmět:	Allylic rearrangement chemistry Radical chemistry.chemical_element Organic chemistry Copper Catalysis
Zdroj:	Catal. Sci. Technol.. 4:1914-1919
ISSN:	2044-4761 2044-4753
DOI:	10.1039/c4cy00271g
Popis:	A multicatalytic system composed of copper complexes and sec-amine compounds is proposed for γ-oxyamination of α,β-unsaturated aldehydes. Using copper complexes in dienamine catalysis expands the scope of the reaction to include TEMPO radicals. Furthermore, copper catalysts oxidize allylic alcohols to form α,β-unsaturated aldehydes, enabling the one-pot oxidation/oxyamination of allylic alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c080f1e2ba201fa4fbe893a994ba599 https://doi.org/10.1039/c4cy00271g Zobrazit plný text záznamu