N,N,N′,N′-Tetrasubstituted Piperazinium Salts of Perfluorinated Acids

Autor:	Dirk-Henning Menz, Hans-Detlev Gilsing, Dietrich Prescher
Rok vydání:	2007
Předmět:	Inorganic Chemistry Chemistry Amphiphile medicine food and beverages Ionic bonding Organic chemistry Ring (chemistry) Chloride Medicinal chemistry medicine.drug
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 633:1676-1678
ISSN:	1521-3749 0044-2313
DOI:	10.1002/zaac.200700102
Popis:	Well crystallized diquaternary piperazinium salts of perfluorocarboxylic acids can be prepared by thermal rearrangement of a primary product obtained from the appropriate fluorinated acid chloride and N,N-dialkylamino-ethanol. The mechanism of the ring closure step is discussed. The synthetic strategy easily gives access to structurally different piperazinium perfluorocarboxylates. The title compounds show surface activity and can be regarded as ionic amphiphiles.
Databáze:	OpenAIRE
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