Anion dependent self-assembly; formation of an octanuclear assembly by templation with the selenite dianion
| Autor: | Christopher Slater, Craig R. Rice, Robert A. Faulkner, Gary Midgley, Christopher J. Clemett |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Chemistry Cryptand chemistry.chemical_element Trigonal pyramidal molecular geometry 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences Ion Inorganic Chemistry Crystallography Tripodal ligand Materials Chemistry Self-assembly Physical and Theoretical Chemistry Selenium |
| Zdroj: | Polyhedron. 182:114483 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2020.114483 |
| Popis: | The tripodal ligand L forms a trinuclear assembly [L2Cu3]6+ in which large and unsymmetrical anions are encapsulated, with the X-ray structures of [L2Cu3(SeO4)]4+ and [L2Cu3(S2O3)]4+ reported. In the presence of the trigonal pyramidal SeO32− anion, both a trinuclear [L2Cu3(SeO3)]4+ and an octametallic assembly [L4Cu8(SeO3)4]8+ are formed and are analysed by X-ray crystallography. The formation of the octanuclear species is a consequence of maximising both the –NH⋯SeO32− interactions and the Cu2+ coordination bonds. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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