Facile interfacial modification via in-situ ultraviolet solidified gel polymer electrolyte for high-performance solid-state lithium ion batteries
| Autor: | J.P. Tu, X.L. Wang, Ruochen Xu, Zhehe Yao, X.H. Xia, Dong Xie, J.B. Wu, Yanjun Xu, S.Z. Zhang, Yang Xia |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Materials science Fabrication Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology 02 engineering and technology Polymer Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Membrane chemistry Chemical engineering Electrode Solid-state battery Electrical and Electronic Engineering Physical and Theoretical Chemistry Cellulose 0210 nano-technology Polarization (electrochemistry) |
| Zdroj: | Journal of Power Sources. 409:31-37 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2018.10.088 |
| Popis: | The poor interfacial contact between electrode materials and electrolyte has become a major obstacle to the development and application of solid-state batteries. In this work, we report a facile method to realize interfacial modification with the help of in-situ ultraviolet solidified gel polymer electrolyte, which is completely compatible with commercial LiFePO4 and cellulose membrane forming stable composite cathode and cellulose membrane-gel polymer electrolyte. Two intimate interfaces between LiFePO4 and gel polymer electrolyte as well as composite cathode and cellulose membrane-based composite electrolyte are achieved to facilitate fast transfer of lithium ions at the interface. The assembled solid-state cell exhibits lower interfacial resistance, reduced polarization, higher rate capability, and more stable cycling performance than other routine counterparts. This work provides a new way for fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries. |
| Databáze: | OpenAIRE |
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