Electronic effects on thermal rearrangement in the Ziegler pyrolysis reaction

Autor:	J. R. Baran, H.S. Isom, Richard J. Lagow
Rok vydání:	1998
Předmět:	Inorganic Chemistry Partial charge Chemistry Chemical shift Thermal Materials Chemistry Electronic effect Moiety Pyrolytic carbon Physical and Theoretical Chemistry Photochemistry Pyrolysis Decomposition
Zdroj:	Inorganic Chemistry Communications. 1:222-224
ISSN:	1387-7003
Popis:	The changes in NMR chemical shifts between TMS 3 CLi versus TMS 3 CH and TMS 3 SiLi versus TMS 3 SiH show that the electronic structures of the two lithiated compounds are vastly different, thereby prohibiting the successful pyrolytic decomposition of TMS 3 CLi to TMS 2 CLi 2 . The moiety to be transferred in the Ziegler pyrolysis reaction must contain at least a partial positive charge for the reaction to be successful.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2ac78ec1ab494d2b296d23daf3d024b3 https://doi.org/10.1016/s1387-7003(98)00059-8 Zobrazit plný text záznamu Full Text from ScienceDirect