Fructose modified synthesis of ZnO nanoparticles and its application for removal of industrial pollutants from water
Autor: | Deepak Kukkar, Jagpreet Singh, Mohit Rawat, Rohit Rawat, Sanjeev Kumar, Gurjinder Singh, Soumen Basu, Sukhwinder Singh Jolly |
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Rok vydání: | 2018 |
Předmět: |
Materials science
Kinetics Hexagonal phase Fructose 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry.chemical_compound Adsorption Chemical engineering chemistry Photocatalysis Electrical and Electronic Engineering Absorption (chemistry) 0210 nano-technology Photodegradation Wurtzite crystal structure |
Zdroj: | Journal of Materials Science: Materials in Electronics. 29:7364-7371 |
ISSN: | 1573-482X 0957-4522 |
DOI: | 10.1007/s10854-018-8726-8 |
Popis: | This research work is an effort towards the purification of industrially polluted water for the savage of the environmental system. Optimized fructose modified ZnO nanoparticles were used as adsorbent as well as a photocatalyst for the removal of dyes from polluted water. Textile synthetic dyes were used as model pollutants. Structural and optical properties of the synthesized fructose modified ZnO nanoparticles were analyzed using XRD, SEM, TEM, and UV–Vis spectrophotometer. Wurtzite hexagonal phase with the quasi-spherical shape of diameter 14–40 nm of fructose modified ZnO nanoparticles were obtained by optimizing various reaction parameters. As compared to the bulk, fructose modified ZnO nanoparticles show a blue shift in the excitation absorption; confirming quantum confinement. The effect of pH, time, and initial dye concentration was investigated on the dye removal efficiency of the synthesized fructose modified ZnO nanoparticles. Through the kinetic study of dye removal, it has been observed that the adsorption and photodegradation phenomenon followed pseudo-first order kinetics. |
Databáze: | OpenAIRE |
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