Deuterium isotope studies on 2,3-dicarbahexaborane(8)

Autor: Thomas Onak, Gary B. Dunks, John R. Spielman, James E. Scott, Richard Warren
Rok vydání: 1968
Předmět:
Zdroj: Inorganic Chemistry. 7:216-218
ISSN: 1520-510X
0020-1669
DOI: 10.1021/ic50060a008
Popis: Deuterium exchange at various positions on the C2B4H8 molecule was studied. D2 exchanges with all boron-bonded hydrogen atoms, and B2D6 in the presence of diglyme exchanges only at the 4-, 6-terminal positions. The (CH3)2C2B4H6-DCl exchange, catalyzed by aluminum chloride, occurs at both apex and base terminal positions. C,C-Dideuterio-2,3-dicarbahexaborane(8), D2C2B4H6, was prepared for comparison of the infrared spectrum. (Author)
Databáze: OpenAIRE