Deuterium isotope studies on 2,3-dicarbahexaborane(8)
Autor: | Thomas Onak, Gary B. Dunks, John R. Spielman, James E. Scott, Richard Warren |
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Rok vydání: | 1968 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 7:216-218 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/ic50060a008 |
Popis: | Deuterium exchange at various positions on the C2B4H8 molecule was studied. D2 exchanges with all boron-bonded hydrogen atoms, and B2D6 in the presence of diglyme exchanges only at the 4-, 6-terminal positions. The (CH3)2C2B4H6-DCl exchange, catalyzed by aluminum chloride, occurs at both apex and base terminal positions. C,C-Dideuterio-2,3-dicarbahexaborane(8), D2C2B4H6, was prepared for comparison of the infrared spectrum. (Author) |
Databáze: | OpenAIRE |
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