Electrochemical synthesis of 1,2,4-triazol-3-thione derivatives: Anodic oxidation of N-thioamidohydrazones

Autor:	Khaled Boujlel, Emmanuel Maisonhaute, Hayet Medini, Mohamed Lamine Benkhoud, Rania Chmekh, Issa Tapsoba
Rok vydání:	2007
Předmět:	Chemistry Supporting electrolyte General Chemical Engineering Inorganic chemistry Electrochemistry Lithium perchlorate Analytical Chemistry Coulometry chemistry.chemical_compound Electron transfer Deprotonation Cyclic voltammetry Acetonitrile
Zdroj:	Journal of Electroanalytical Chemistry. 599:85-90
ISSN:	1572-6657
DOI:	10.1016/j.jelechem.2006.09.014
Popis:	The electrochemical oxidation of N-thioamidohydrazone, 1, was undertaken at platinum electrode in acetonitrile containing lithium perchlorate as supporting electrolyte and monitored via cyclic voltammetry and controlled potential coulometry. An overall process consisting of an irreversible two electron transfer involving, in absence or presence of a base, deprotonation and intramolecular cyclization reactions enables the formation of 1,2,4-triazol-3-thione in a satisfactory yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::278473467ac7851d7528a45b8001e17b https://doi.org/10.1016/j.jelechem.2006.09.014 Zobrazit plný text záznamu Full Text from ScienceDirect