Thermodynamic properties of binary liquid mixtures containing aromatic alcohol and aliphatic amines at different temperatures
| Autor: | Rekha Gaba, A. Shakila, V. Pandiyan, S. Ravikumar |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Work (thermodynamics)
Materials science Isentropic process Intermolecular force Thermodynamics 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry.chemical_compound Molar volume chemistry Benzyl alcohol Speed of sound Materials Chemistry Amine gas treating Physical and Theoretical Chemistry Fourier transform infrared spectroscopy 0210 nano-technology Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 285:279-287 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2019.04.064 |
| Popis: | As an extension of our previous work, thermodynamic and acoustic properties of binary mixtures of benzyl alcohol with propyl amine, di-propyl amine, diiso-propyl amine and tri-propyl amine have been investigated by measuring density and speed of sound data at four temperatures (T = 303.15, 308.15, 313.15 and 318.15 K) and pressure (P = 0.1 MPa) over the entire composition range. These data have been utilized to calculate excess parameters like excess molar volume (VmE), excess isentropic compression (KSE ) and excess speed of sound (uE) for all the systems.All the excess parameters have been correlated by Redlich-Kister equation. Further, to analyse the experimental results theoretical treatment of the data has also been done by using Prigogine–Flory–Patterson (PFP) theory, intermolecular free length theory and collision frequency theory. Results were also supported by FTIR studies of equimolar binary liquid mixtures. |
| Databáze: | OpenAIRE |
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