Nitration equilibrium in the meso-erythritol-aqueous nitric acid system

Autor: G. B. Manelis, L. P. Andrienko, G. V. Lagodzinskaya, Yu. I. Rubtsov, N. G. Yunda, L. T. Eremenko, A. I. Kazakov, A. M. Korolev
Rok vydání: 1991
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:1966-1971
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00963488
Popis: Twelve equilibrium constants have been measured from 16 for sequential-parallel reactions in meso-erythritol nitration to the fully nitrated compound in aqueous HNO3. Free-energy changes during nitration of the aliphatic polyatomic alcohols, glycerol and meso-erythritol, are highest when diprimary dinitrates (NOON) and (NON) are produced.
Databáze: OpenAIRE