Nitration equilibrium in the meso-erythritol-aqueous nitric acid system
Autor: | G. B. Manelis, L. P. Andrienko, G. V. Lagodzinskaya, Yu. I. Rubtsov, N. G. Yunda, L. T. Eremenko, A. I. Kazakov, A. M. Korolev |
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Rok vydání: | 1991 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:1966-1971 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00963488 |
Popis: | Twelve equilibrium constants have been measured from 16 for sequential-parallel reactions in meso-erythritol nitration to the fully nitrated compound in aqueous HNO3. Free-energy changes during nitration of the aliphatic polyatomic alcohols, glycerol and meso-erythritol, are highest when diprimary dinitrates (NOON) and (NON) are produced. |
Databáze: | OpenAIRE |
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