| Autor: |
Da-Peng Xu, Shu-E Liu, Zhiguo Liu, Quanyong Wang, Gongmu Zhang, Wenhui Su, Zhe Lü, Yankun Tang |
| Rok vydání: |
2002 |
| Předmět: |
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| Zdroj: |
Journal of Physics: Condensed Matter. 14:11265-11268 |
| ISSN: |
0953-8984 |
| DOI: |
10.1088/0953-8984/14/44/465 |
| Popis: |
Using nanoparticles of CeO2 and ZrO2 prepared by a chemical precipitation method as starting materials, single-phase cubic Ce0.5Zr0.5O2 solid solution (c-Ce0.5Zr0.5O2) has been synthesized under 3.1 GPa at 1073 K for the first time. The EPR and XPS measurements show that there exists no Ce3+, in it and that the Ce4+ has not been reduced to Ce3+ after annealing. The transport mechanism is ionic for the c-Ce0.5Zr0.5O2. The bulk conductivity is the same as that of CeO2, but smaller than that of Y2O3-stabilized ZrO2. (Some figures in this article are in colour only in the electronic version). |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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