A novel mixed valence tetranuclear nitrosyl complex bridged by tetraoxomolybdate

Autor:	Tomoko Hashimoto, Toshiaki Yonemura, Tomoharu Ama, Mayumi Hasegawa, Tamami Ikenoue, Hiroshi Kawaguchi
Rok vydání:	2006
Předmět:	Inorganic Chemistry Bridging oxygen Crystallography Valence (chemistry) chemistry Molybdenum Ligand Stereochemistry Materials Chemistry chemistry.chemical_element Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry Communications. 9:183-186
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2005.10.033
Popis:	The reaction of the molybdenum–dinitrosyl complexes with PPh3, using 2-pyrimidinethiolate (pymt) or 2-pyridinethiolate (pyt) as a thiolate ligand, was found to produce a dinuclear complex [{(ON)MoL2}2(μ-OH)2] (1) (L = pymt or pyt) and Ph3PO. In addition, the first reported example of a mixed valence molybdenum–nitrosyl tetranuclear complex, [Ph3POH]2[{(ON)Mo(pymt)2}2(μ-MoO4)2] (2), was produced by the reaction of 1(pymt) with Ph3PO. This is the first published nitrosyl complex containing both tetraoxomolybdate and thiolato ligands. The molybdenum and bridging oxygen atoms formed a novel eight-membered ring with a central porous structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::252dff7d015a1d8aa7c68a8ff88b5294 https://doi.org/10.1016/j.inoche.2005.10.033 Zobrazit plný text záznamu Full Text from ScienceDirect