Preparation of α-fluoro-β-per(poly)fluoroalkyl-substituted enol ethers
| Autor: | Donald J. Burton, Alagappan Thenappan |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Carboxylic acid Organic Chemistry Infrared spectroscopy Nuclear magnetic resonance spectroscopy Mass spectrometry Biochemistry Enol Ethyl formate Ion Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Journal of Fluorine Chemistry. 77:45-50 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/0022-1139(95)03382-3 |
| Popis: | Fluorocarboethoxymethylene tri-n-butylphosphorane, Bu3P=CFCOOEt (3), reacts with per- and poly-fluoroalkyl-substituted carboxylic acid esters, ethyl formate and γ-butyrolactone to give the corresponding enol ethers, RFC (OEt)=CFCOOEt (4), in good yield. Non-activated esters failed to react with 3. With the anion derived from ethyl diethylphosphonofluoroacetate, (EtO)2P(O)CFHCOOEt (5), a mixture of 4 and β-ketoesters, RFC(O)CFHCOOEt (7), is formed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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