Synthesis of a novel titanium complex catalyst and its catalytic performance for olefin polymerization
| Autor: | Yajiao Wang, Yanliu Dang, Yun Zhao, Chaoxiang Wang, Hansheng Li, Wu Qin, Qingze Jiao |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Ethylene 010405 organic chemistry Chemistry General Chemical Engineering General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Coordination complex End-group chemistry.chemical_compound Chain-growth polymerization Polymerization Phenyl salicylate Polymer chemistry Copolymer |
| Zdroj: | Russian Journal of Applied Chemistry. 88:1723-1727 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427215100262 |
| Popis: | A phenoxy-ester Ti based complex of bis[5-methyl-3-trimethylsilyl phenyl salicylate]titanium(IV) dichloride was prepared for olefin polymerization. The structures of the ligand and the complex were characterized using infrared spectrometer, nuclear magnetic resonance, and mass spectrum. The novel [O,O]bidentate coordination compound was used as the catalyst for ethylene and propylene polymerization together with i-Bu3Al/Ph3CB(C6F5)4 as the cocatalyst in toluene. It was found that the as-prepared catalyst displayed activity for both polymerization and copolymerization. As-obtained ethylene propylene copolymer was random copolymer. The glass transition temperature of the copolymer was -43.3°C. |
| Databáze: | OpenAIRE |
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