A new photoluminescent CuI2N6 chromophore

Autor:	Derek A. Tocher, Prakriti Ranjan Bangal, Bikas C. Maiti, Israel Goldberg, Shubhamoy Chowdhury, Dipankar Datta, Sanjoy K. Chowdhury, Golam Mostafa, Amitabha Sarkar, Nitin Chattopadhyay, Michael G. B. Drew, Goutam K. Patra, Sankar Chakravorti
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Photoluminescence chemistry business.industry Materials Chemistry Optoelectronics Quantum yield General Chemistry Methanol Chromophore business Photochemistry Catalysis
Zdroj:	New Journal of Chemistry. 25:1371-1373
ISSN:	1369-9261 1144-0546
DOI:	10.1039/b105442m
Popis:	A novel CuI2N6 chromophore has been isolated with 2,2′-bis[(4R)-phenyl]-1,3-oxazoline (L) in the optically pure triple-stranded helicate [Cu2L3](ClO4)2, which displays photoluminescence in methanol at room temperature (emission maximum λem = 385 nm; quantum yield ϕ = 1.6 × 10−4; lifetime τ ≈ 2 ns) as well as at 77 K (λem = 430 nm; τ = 0.89 ± 0.13 s).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2467d3f56d3e25a5a5a6a30a3f883260 https://doi.org/10.1039/b105442m Zobrazit plný text záznamu