I2 as a probe for aromatic rings in phenylene-bridged periodic mesoporous organosilica

Autor:	Beatrice Camarota, Barbara Onida, Yasutomo Goto, Shinji Inagaki, Edoardo Garrone
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Mesoporous organosilica Crystallography Adsorption chemistry Phenylene Organic chemistry Electron donor Aromaticity Hybrid material PMOS logic Amorphous solid
DOI:	10.1016/s0167-2991(08)80055-9
Popis:	Periodic Mesoporous Organosilicas (PMOs) represent a new class of organic-inorganic hybrid materials suitable for a broad range of applications. In the present contribution iodine vapours were adsorbed on phenylene-bridged PMOs with hexagonal 2D pore structure. The adsorption was followed by UV-visible spectroscopy, and information was obtained concerning the electron donor ability of the structural aromatic rings. Traces of I 3 − species were also detected. A comparison between phenylene-bridged PMOs with two different degrees of molecular order in the walls revealed that aromatic rings in the material with amorphous walls are more available to interaction with iodine.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::244d34e76538ebfb127f22e5bab26cb6 https://doi.org/10.1016/s0167-2991(08)80055-9 Zobrazit plný text záznamu