2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-Dioxide (PASO2). Comparative Structural and Reactivity Investigation with the Water-Soluble Phosphine Ligand 1,3,5-triaza-7-phosphaadamantane (PTA)

Autor:	and Jason C. Yarbrough, Samuel J. Lewis, Donald J. Darensbourg
Rok vydání:	2003
Předmět:	Ligand Organic Chemistry Alkylation Resonance (chemistry) Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Spectroscopy Derivative (chemistry) Phosphine Methyl iodide
Zdroj:	Organometallics. 22:2050-2056
ISSN:	1520-6041 0276-7333
Popis:	The derivative 2-thia-1,3,5-triaza-phosphaadamantane 2,2-dioxide (PASO2) has been characterized by spectroscopy and by X-ray crystallography. Unlike its PTA (1,3,5-triaza-7-phosphaadamantane) analogue, replacement of a −CH2− unit in PTA with −SO2− renders PASO2 largely insoluble in water at ambient temperature (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::238f8d80bb47c5575bd7853d310a340a https://doi.org/10.1021/om0300225 Zobrazit plný text záznamu