Low-frequency lattice vibrations of δ-GaSe compared to ϵ- and γ-polytypes

Autor: Arno Kuhn, Karel Kunc, Alain Polian
Rok vydání: 1976
Předmět:
Zdroj: Solid State Communications. 19:1079-1082
ISSN: 0038-1098
Popis: Raman spectra of the new polytype 5-GaSe are given in the low-frequency region (co < 60 cm-1) and their relation to lattice vibrations of the simpler polytypes 3', e is discussed. A simple lattice dynamical model is used to describe the phonon modes in all 3 modifications. First observation of Davydov splitting in e-GaSe is reported. Particular weakness of one component of this doublet is shown to be a consequence of the specific "molecular" nature of layer crystal.
Databáze: OpenAIRE