Nanowell device for the electrical characterization of metal–molecule–metal junctions

Autor: Nabanita Majumdar, Nadine Gergel, David Routenberg, Bin Li, James M. Tour, Lin Pu, Lloyd R. Harriott, Yuxing Yao, John C. Bean
Rok vydání: 2005
Předmět:
Zdroj: Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures. 23:1417
ISSN: 0734-211X
Popis: A nanowell device for the electrical characterization of metal–molecule–metal junctions was built using readily available processing tools and techniques. This device consisted of a nanoscale well, with a gold bottom, filled with a self-assembling monolayer of organic molecules, and capped with titanium and gold. Focused ion beam technology was used to fabricate the well with a width less than the grain size of gold. This nanowell improved the device performance dramatically by reducing the chances of pinhole formation in the self-assembling monolayer on the bottom gold electrode. Unlike some established characterization techniques, including conducting probe atomic force microscopy and scanning tunneling microscopy, the nanowell device has the potential for future circuit integration. The effectiveness of the device was confirmed by testing I–V characteristics of alkanethiols and oligomeric arylthiols. The alkanethiol current was exponentially dependent on chain length with a decay factor (β) that ranged...
Databáze: OpenAIRE