The use of 57Fe Mössbauer spectroscopy in assigning the types of iron carbonyl units present in Fe-containing clusters

Autor:	R.P. Brint, Mary P. Collins, F.A. Deeney, Trevor R. Spalding
Rok vydání:	1983
Předmět:	Cyclopentadiene Chemistry Organic Chemistry Inorganic chemistry Solid-state Bridging ligand Biochemistry Inorganic Chemistry Crystallography chemistry.chemical_compound Mössbauer spectroscopy Materials Chemistry Molecule Mossbauer spectra Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 258:C57-C60
ISSN:	0022-328X
Popis:	Comparison of the 57 Fe Mossbauer spectra of series of related M 3 , M 4 and M 5 clusters has enabled correlations to be made between the Mossbauer parameters δ (isomer shift) and q (quandrupole splitting), and the type of iron site present, viz. Fe(CO) n t , Fe(CO) m br or Fe(CO) n t (CO) m br H br (t  terminal, br  bridging ligand).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f70d3898eea377c155e7bd169bf1bd5 https://doi.org/10.1016/s0022-328x(00)99287-8 Zobrazit plný text záznamu