ChemInform Abstract: Asymmetric Synthesis of Stannanes and Silanes via Reaction of Chiral Imidazolidinone Carbene Complexes with Group 14 Hydrides

Autor:	Mark Parisi, Ilia A. Guzei, Arnold L. Rheingold, William D. Wulff, Aaron Solo
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Transmetalation Silanes Chemistry Imidazolidinone Transition metal carbene complex Polymer chemistry Enantioselective synthesis Organic chemistry General Medicine Alkylation Enantiomeric excess Carbene
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199850146
Popis:	Chiral silanes and stannanes can be obtained with high optical purity from the 1,1-addition reactions of nonchiral silanes and stannanes with Fischer carbene complexes substituted with a chiral imidazolidinone auxiliary. The α-stannyl imidazolidinone products will undergo transmetalation and alkylation with high stereoselection with reactive electrophiles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1e3e9fb2b3868dae2ade2dfbd5948636 https://doi.org/10.1002/chin.199850146 Zobrazit plný text záznamu Plný text