Synthesis, Characterization, and Structure of a Silver(I) Compound With Thymine

Autor:	Ji-Dong Lou, Xiu Lian Lu, Yi-Feng Zhou, Li-Hong Huang, Xiao-Hong Chen, Ping-Sheng Nong
Rok vydání:	2012
Předmět:	Element analysis Ligand Hydrogen bond Stereochemistry Intermolecular force Crystal structure Ion Characterization (materials science) Thymine Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Physical and Theoretical Chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 42:313-316
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533174.2011.610092
Popis:	The interaction of [Ag(PPh3)2(CH3COO)] (1) with thymine led to the displacement of the acetate ligand forming the mononuclear compound [Ag(PPh3)2(C5H5N2O2)] (2). This compound has been characterized by IR, NMR, element analysis, and X-ray crystallographic analysis. Crystal structure of 2 shows each Ag ion is three-coordinated by two P atoms of the triphenylphosphino ligands and one N atoms of the thymine, which is stabilized by two intermolecular N-H…O and O-H…O hydrogen bonding interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1c2876ab8c3f0f23c3ae2df1996d00b3 https://doi.org/10.1080/15533174.2011.610092 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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