Synthesis of 15N-labeled heterocycles via the cleavage of C–N bonds of anilines and glycine-15N

Autor:	Qiuqin He, He Jiwen, Hao Guo, Renhua Fan, Xing-Guo Zhang
Rok vydání:	2021
Předmět:	Chemistry Metals and Alloys Aromatization chemistry.chemical_element General Chemistry Cleavage (embryo) Medicinal chemistry Nitrogen Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Glycine Materials Chemistry Ceramics and Composites Bond cleavage
Zdroj:	Chemical Communications. 57:5442-5445
ISSN:	1364-548X 1359-7345
Popis:	A nitrogen replacement process that directly incorporates the 15N atom of glycine-15N into anilines was reported. The process involves a Csp2–N bond cleavage of anilines driven by dearomatization and a Csp3–N bond cleavage of glycine-15N driven by aromatization. A variety of 15N-labeled aromatic heterocycles can be prepared via this process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1c14243856d5404317dfdea7ecac5055 https://doi.org/10.1039/d1cc01734a Zobrazit plný text záznamu