The stereospecific addition of dienes to palladium chloride

Autor:	H.C. Volger, Arjan P. Kouwenhoven, P.W.N.M. van Leeuwen, J. Lukas
Rok vydání:	1973
Předmět:	inorganic chemicals Diene Organic Chemistry Diastereomer Palladium chloride Biochemistry Inorganic Chemistry chemistry.chemical_compound Stereospecificity chemistry Materials Chemistry Organic chemistry Epimer Solvolysis Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 47:153-163
ISSN:	0022-328X
Popis:	Using 2,4-hexadiene as a model compound we have shown that dienes add to palladium chloride in a stereospecific way. The three diene isomers react to give a pair of epimeric π-allylpalladium diastereomers, one of which is formed from the cis,trans-diene, the other from either the trans,trans or the cis,cis-isomer. The mechanisms of the epimerization and solvolysis of the products have been studied, and the reactions found to proceed via a diene-palladium complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1bf15572128ac18fb613579156269aaa https://doi.org/10.1016/s0022-328x(00)92851-1 Zobrazit plný text záznamu