Structural characterization of various dirhodium compounds using fast atom bombardment and collision-induced dissociation mass spectrometry

Autor:	Bill Boggess, Clifton Woods, Johnny D. Reynolds, Kelsey D. Cook, James L. E. Burn
Rok vydání:	1993
Předmět:	Inorganic Chemistry Fragmentation (mass spectrometry) Collision-induced dissociation Lability Chemistry Mass spectrum Analytical chemistry Molecule Physical and Theoretical Chemistry Fast atom bombardment Photochemistry Mass spectrometry Dissociation (chemistry)
Zdroj:	Inorganic Chemistry. 32:5517-5521
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00076a018
Popis:	Fast atom bombardment (FAB) and collision-induced dissociation (CID) tandem mass spectra of a series of novel pyrazolato-bridged dirhodium A-frame compounds provide structure confirmation and useful information concerning the structural dependence of lability, based upon fragmentation pathways. CID mass spectra indicate that FAB matrix- and beam-induced reduction chemistry can alter the energy and/or the structure of the precursor molecules. However, it appears that FAB matrix- and beam-induced oxidation chemistry does not do so detectably
Databáze:	OpenAIRE
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