X-ray photoelectron spectroscopy of Pd/γ-alumina and Pd foil after catalytic methane oxidation

Autor: L. P. Haack, K. Otto
Rok vydání: 1995
Předmět:
Zdroj: Catalysis Letters. 34:31-40
ISSN: 1572-879X
1011-372X
DOI: 10.1007/bf00808319
Popis: Samples of palladium supported onγ-alumina and a palladium foil were used as catalysts for methane oxidation at 550° C. The samples were quenched quickly in the reaction chamber to room temperature in flowing Ar and then transferred in vacuo for XPS analysis. Structure sensitivity was manifest from an increase in PdO stability and a decrease in carbon deposition relative to Pd with increasing particle size. The results were compared with recent ellipsometric data.
Databáze: OpenAIRE