| Popis: |
The 12 eV, 350 K electron impact ionisation mass spectra of 28 aliphatic amides of diverse structure are reported and discussed. All the spectra contain strong molecular ion signals, often corresponding to the base peak, thus providing unequivocal molecular mass information. Structural information is also accessible from specific primary fragmentations associated with the substituent(s) attached to the carbon and nitrogen atom of the amide group. Alkene elimination from the ionised amides takes place most readily from the substituent attached to the carbon atom via a McLafferty rearrangement, but it also occurs to a lesser degree from some ionised amides with no γ-hydrogen atom. In contrast, alkyl radical loss is usually associated with fission of an N-alkyl group, typically by apparent α-cleavage. Other primary fragmentations of significance include expulsion of an alkenyl radical derived from an N-alkyl substituent. In one such process, the eliminated alkenyl radical has one carbon atom fewer than the i... |
