Mineralization of aqueous phenolate solutions: A combination of irradiation treatment and wet oxidation

Autor: Mounir Chamam, Csilla Magdolna Földváry, Arezoo M. Hosseini, László Wojnárovits, Erzsébet Takács, Antal Tungler
Rok vydání: 2012
Předmět:
Zdroj: Radiation Physics and Chemistry. 81:1484-1488
ISSN: 0969-806X
DOI: 10.1016/j.radphyschem.2011.11.013
Popis: Wet oxidation (high-temperature, high-pressure oxidation of organic wastes in aqueous solution) and radiation technology were combined in γ-ray and electron beam induced oxidation of 4×10−4–1×10−2 mol dm−3 Na-phenolate solutions in a wide O2 concentration (1–20 bar pressure) and absorbed dose (0–50 kGy) range. Most experiments were made in stainless steel high pressure autoclave equipped with magnetic stirrer. The rate of oxidation was followed by chemical oxygen demand and total organic carbon content measurements. The rate was similar in γ-ray and pulsed electron beam irradiation and increased with O2 concentration in the liquid.
Databáze: OpenAIRE