Autor: |
Khatereh Ghorbanpour, Kazem D. Safa |
Rok vydání: |
2013 |
Předmět: |
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Zdroj: |
Journal of Organometallic Chemistry. :214-218 |
ISSN: |
0022-328X |
Popis: |
A new type of chemistry of carbon disulfide proceeding by way of nucleophilic attack of tris(trimethylsilyl)methyllithium (TsiLi) at carbon of carbon disulfide is reported. The treatment of TsiLi and CS 2 with some symmetrical and unsymmetrical benzyl halides has yielded novel multifunctional compounds with SiMe 3 , SH and C S groups. The obtained compounds (mercapto-silyl-thiones) have been produced with unusual rearrangement that is apparently the first example of such migration of sulphur to carbon atom. These reactions have high selectivity and the yields are quantitative. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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