Synthesis of Higher-Nuclearity Clusters by Use of Small Cluster Units as Building Blocks: Synthesis and X-Ray Structure Analysis of [ClCCo3(CO)8]2(μ-dppe) and [ClCCo3(CO)7][ClCCo3(CO)8](μ-TRIPHOS) (dppe = 1,2-bis(diphenylphosphino)ethane; TRIPHOS = bis(2-diphenylphosphinoethyl)phenylphosphine)

Autor:	Mayumi Otsuka, Satoru Onaka
Rok vydání:	1995
Předmět:	Stereochemistry chemistry.chemical_element General Chemistry Triphos chemistry.chemical_compound Crystallography 1 2-Bis(diphenylphosphino)ethane chemistry Phenylphosphine Cluster (physics) Molecule Single crystal Cobalt Derivative (chemistry)
Zdroj:	Chemistry Letters. 24:269-270
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1995.269
Popis:	Two ClCCo3(CO)9 units are, after treatment with Me3NO, linked at basal cobalt atoms by dppe spacer to yield [ClCCo3(CO)8]2(μ-dppe) and by TRIPHOS to yield [ClCCo3(CO)7][ClCCo3(CO)8](μ-TRIPHOS); they are characterized by single crystal X-ray molecular structure analysis and two Cl atoms in the TRIPHOS derivative are found to be located in close proximity.
Databáze:	OpenAIRE
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