Evidence for proton tunneling in the strong base catalyzed elimination reaction of .beta.-phenylethyl substrates

Autor:	Kazimiera A. Wilk, Harold Kwart
Rok vydání:	1985
Předmět:	Tunnel effect Elimination reaction chemistry.chemical_compound Ethanol Deuterium Chemistry Stereochemistry Organic Chemistry Kinetic isotope effect Proton tunneling Medicinal chemistry Catalysis
Zdroj:	The Journal of Organic Chemistry. 50:817-820
ISSN:	1520-6904 0022-3263
Popis:	L'etude est faite pour les composes C 6 H 5 CH 2 CH 2 X avec X=Br, p-CH 3 C 6 H 4 SO 3 , + S(CH 3 ) 2 , + N(CH 3 ) 3 . On applique les criteres TDKIE aux eliminations E2 (TDKIE= influence de la temperature sur l'effet isotopique cinetique H/D)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1642171b6af73473d31cdff30d7b6484 https://doi.org/10.1021/jo00206a018 Zobrazit plný text záznamu