Multifunctional Gas Adsorption and Photocatalytic Degradation Based on a Porous Metal-Organic Framework Material
| Autor: | E. H. Zhou, Jun-Cheng Jin, J. L. Jia, Z. D. Luo, J. Q. Liu, B. H. Li, B. W. Wu |
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| Rok vydání: | 2018 |
| Předmět: |
Biphenyl
Porous metal Ligand General Chemical Engineering Methyl violet 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Adsorption chemistry Polymer chemistry Degradation (geology) Moiety 0210 nano-technology Photocatalytic degradation |
| Zdroj: | Russian Journal of Coordination Chemistry. 44:173-178 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328418030077 |
| Popis: | The reaction of Cu(NO3)2 · 3H2O with rigid ligand 4'-(1H-tetrazol-5-yl)-[1,1'-biphenyl]-3,5-dicarboxylic acid (H3L) gave a new metal-organic framework of [Cu2(μ3-OH)(L)(H2O)2] n (I) (CIF file CCDC no. 1533273). Complex I has a truncated cuboctahedra that was connected by trigonal Cu3O(N4CR)3 trimers using each tetrazolate (N4CR) moiety and shows a overall 3D nnt net with (6.82)6(83)2(62.84)3 topology. The properties of gas adsorption and the degradation of the methyl violet have been examined. |
| Databáze: | OpenAIRE |
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