Prediction of thermodynamic data for radium suitable for thermodynamic database for radioactive waste management using an electrostatic model and correlation with ionic radii among alkaline earth metals
Autor: | Yasushi Yoshida, Akira Kitamura |
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Rok vydání: | 2021 |
Předmět: |
Strontium
Alkaline earth metal Materials science Ionic radius Standard molar entropy Health Toxicology and Mutagenesis Public Health Environmental and Occupational Health chemistry.chemical_element Thermodynamics Radioactive waste Barium 010403 inorganic & nuclear chemistry 01 natural sciences Pollution 0104 chemical sciences Analytical Chemistry Radium Standard Gibbs free energy of formation Nuclear Energy and Engineering chemistry Radiology Nuclear Medicine and imaging Physics::Atomic Physics Spectroscopy |
Zdroj: | Journal of Radioanalytical and Nuclear Chemistry. 327:839-845 |
ISSN: | 1588-2780 0236-5731 |
DOI: | 10.1007/s10967-020-07527-5 |
Popis: | Thermodynamic data for radium for radioactive waste management have been predicted using an electrostatic model and correlation with the ionic radii of the alkaline earth metals. Estimation of the standard Gibbs free energy of formation and standard molar entropy of aqueous radium species and compounds has been based on such approaches as extrapolation of the thermodynamic properties of strontium and barium, and use of a model of ion pair formation. The predicted thermodynamic data for radium have been compared with previously reported values. |
Databáze: | OpenAIRE |
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