Thermal stability, crystallization and soft magnetic properties of Fe-P-C-based glassy alloys
| Autor: | Yaxin Di, Zhe Fang, Shaokang Guan, Jianfeng Wang, Tao Zhang |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010302 applied physics
Materials science Amorphous metal Metallurgy Alloy Analytical chemistry Nucleation 02 engineering and technology Coercivity engineering.material 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Electronic Optical and Magnetic Materials law.invention law 0103 physical sciences Materials Chemistry Ceramics and Composites engineering Thermal stability Crystallization 0210 nano-technology Glass transition Supercooling |
| Zdroj: | Journal of Non-Crystalline Solids. 454:39-45 |
| ISSN: | 0022-3093 |
| DOI: | 10.1016/j.jnoncrysol.2016.10.014 |
| Popis: | Thermal stability, crystallization and magnetic properties of Fe 80 P 11 C 9 , Fe 80 P 9 B 2 C 9 , and Fe 77 Al 3 P 9 B 2 C 9 glassy alloys were investigated. The relationships of glass-forming ability (GFA) with thermal properties and crystallization, magnetic properties with crystallization were also discussed. The variation trend of GFA for these glassy alloys is in agreement with the reduced glass transition temperature. The annealing experiment shows that the primary precipitation phase both for the Fe 80 P 11 C 9 and Fe 80 P 9 B 2 C 9 glassy alloys is α-Fe, and the addition of small amounts of Al is effective for suppression of the formation of α-Fe phase, resulting in the extension of supercooled liquid region and significant enhancement of GFA. The activation energy for primary crystallization calculated by Kissinger's equation indicates the addition of B in Fe–P–C alloy or Al in Fe–P–B–C alloy makes nucleation more difficult, which is responsible for the enhancement of GFA. In addition, it was found that the crystallized Fe 80 P 9 B 2 C 9 specimen with ultrafine α-Fe grains exhibits high saturation magnetic polarization of up to 1.60 T and low coercive force of about 3.0 A/m. |
| Databáze: | OpenAIRE |
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