Polymorphs of a 1:1 Cocrystal with Tunnel and Layer Structures: p,p‘-Biphenol/Dimethyl Sulfoxide
Autor: | Kenneth D. M. Harris, and Benson M. Kariuki, Shinbyoung Ahn |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Crystal Growth & Design. 1:107-111 |
ISSN: | 1528-7505 1528-7483 |
DOI: | 10.1021/cg000010b |
Popis: | Two polymorphs of the 1:1 cocrystal formed between p,p‘-biphenol and dimethyl sulfoxide (DMSO) have been discovered. One polymorph has a tunnel type structure, which can be considered to comprise tunnels formed from p,p‘-biphenol molecules accommodating the DMSO molecules as guests. The other polymorph has a layered structure, comprising layers of p,p‘-biphenol molecules and layers of DMSO molecules. In both structures, there is direct hydrogen bonding between the p,p‘-biphenol and DMSO components of the cocrystal. The general utility of the p,p‘-biphenol molecule as a component in crystal engineering strategies is discussed. |
Databáze: | OpenAIRE |
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