A thermodynamic analysis of the solubility of gases in water at high pressures and supercritical temperatures

Autor:	A. N. Vul’fson, O. O. Borodin
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Work (thermodynamics) Real gas chemistry Thermodynamics Physical and Theoretical Chemistry Solubility Material properties Methane Supercritical fluid Thermodynamic process Henry's law
Zdroj:	Russian Journal of Physical Chemistry A. 81:510-514
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024407040024
Popis:	A one-parameter form of the Henry law is suggested to describe the solution of real gases in water over a fairly wide range of temperature and pressure variations. The thermodynamic derivation of the Henry law is based on the Van’t Hoff model of concentrated solutions of gases. The analytic approach developed in this work is a variant of rigorous thermodynamic theory that refines and generalizes the Krichevskii-Kazarnovskii equation. The thermodynamic theory suggested is compared with the experimental data on the solution of methane and nitrogen in water.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::13619c35d57f18ea3c27eaf8c6b34da2 https://doi.org/10.1134/s0036024407040024 Zobrazit plný text záznamu Full text from SpringerLink