Self-ignition combustion synthesis of TiFe1−xMnx hydrogen storage alloy
| Autor: | Noriyuki Okinaka, Ryuta Wakabayashi, Shino Sasaki, Tomohiro Akiyama, Naoto Yasuda |
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| Rok vydání: | 2009 |
| Předmět: |
Exothermic reaction
Range (particle radiation) Hydrogen Renewable Energy Sustainability and the Environment Chemistry Cryo-adsorption Alloy Analytical chemistry Energy Engineering and Power Technology chemistry.chemical_element engineering.material Condensed Matter Physics Combustion law.invention Ignition system Hydrogen storage Fuel Technology law engineering Nuclear chemistry |
| Zdroj: | International Journal of Hydrogen Energy. 34:9122-9127 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2009.08.102 |
| Popis: | The paper describes the self-ignition combustion synthesis (SICS) of the hydrogen storage alloy TiFe 1−x Mn x (X = 0, 0.1, 0.2, 0.3, and 0.5) in a hydrogen atmosphere, where the hydrogenation properties of the products are mainly examined. In the experiments, the well-mixed powders of Ti, Fe, and Mn in the molar ratio of 1:1-X:X were uniformly heated up to 1473 K, and then were cooled naturally in pressurized hydrogen at 0.9 MPa. All products were successfully synthesized by utilizing the exothermic reaction, which occurred at around 1358 K. The XRD analysis showed that SICS generated TiFe 1−x Mn x in the range of X value from 0 to 0.3. All SICSed products absorbed hydrogen smoothly at 298 K at an initial pressure of 4.1 MPa. Most significantly, TiFe 0.8 Mn 0.2 improved the dual plateau property. The results revealed that SICS was quite effective for producing the hydrogen storage alloy TiFe 1−x Mn x . |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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