Thermally Reversible Dendronized Linear AB Step-Polymers via 'Click' Chemistry

Autor:	Dominic V. McGrath, Nathan W. Polaske, James R. McElhanon
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Polymer Retro-Diels–Alder reaction Cycloaddition Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Polymerization Dendrimer Polymer chemistry Materials Chemistry Click chemistry Maleimide
Zdroj:	Macromolecules. 44:3203-3210
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma200296t
Popis:	The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a−c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide−alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels−Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a−c was studied by GPC.
Databáze:	OpenAIRE
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