Investigation of the catalytic properties of platinum-tin complexes containing dimethyl sulfoxide, dimethylformamide, or dimethylacetamide

Autor: L. Kh. Freidlin, Ya. G. Mukhtarov, A. N. Shan'ko, Yu. N. Kukushkin, P. G. Antonov, N. V. Borunova
Rok vydání: 1976
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:948-952
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00921970
Popis: 1. The catalytic activity of new complexes of Pt (II)-Sn (II) with dimethylacetamide and DMF in isomerization and hydrogenation reactions of compounds containing a C=C bond is greater than the activity of the Pt-SnCl3 complex by a factor of 4–5. 2. All the examined complexes catalyzed the selective hydrogenation of phenylacetylene to styrene, and diphenylacetylene to diphenylethane passing through the stilbene stage.
Databáze: OpenAIRE