Investigation of the catalytic properties of platinum-tin complexes containing dimethyl sulfoxide, dimethylformamide, or dimethylacetamide
Autor: | L. Kh. Freidlin, Ya. G. Mukhtarov, A. N. Shan'ko, Yu. N. Kukushkin, P. G. Antonov, N. V. Borunova |
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Rok vydání: | 1976 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:948-952 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00921970 |
Popis: | 1. The catalytic activity of new complexes of Pt (II)-Sn (II) with dimethylacetamide and DMF in isomerization and hydrogenation reactions of compounds containing a C=C bond is greater than the activity of the Pt-SnCl3 complex by a factor of 4–5. 2. All the examined complexes catalyzed the selective hydrogenation of phenylacetylene to styrene, and diphenylacetylene to diphenylethane passing through the stilbene stage. |
Databáze: | OpenAIRE |
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