| Autor: |
Christoph Schick, Bernhard Wunderlich, René Androsch, Daniela Mileva, Evgeny Zhuravlev |
| Rok vydání: |
2011 |
| Předmět: |
|
| Zdroj: |
Polymer. 52:1107-1115 |
| ISSN: |
0032-3861 |
| DOI: |
10.1016/j.polymer.2011.01.021 |
| Popis: |
Fast scanning chip calorimetry (FSC) has been employed to study the kinetics of formation of the mesophase of random copolymers of propylene and 1-butene from the glassy amorphous state and its reorganization on heating. The experiments performed consistently prove a distinct decrease of the rate of mesophase formation with increasing concentration of 1-butene chain defects. The time required for isothermal mesophase formation at 300 K is of the order of 0.1 s in case of the homopolymer, while it is prolonged by one order of magnitude to 1 s in the copolymer with 11 mol-% 1-butene. Similar, cold-ordering of amorphous structure on continuous heating at 1000 K s −1 is only completed in the homopolymer while it is almost completely suppressed in the random copolymer containing about 11 mol-% 1-butene. The perfection of the mesophase and/or its reorganization into crystals is faster in the homopolymer than in copolymers containing 1-butene. The critical heating rate for complete inhibition of perfection and reorganization is reduced from about 40,000 K s −1 in the homopolymer to about 10,000 K s −1 in copolymers. The reduced rate of mesophase formation in random copolymers of propylene and 1-butene is attributed to the decrease of the thermodynamic driving force for the phase transformation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect