Pincer-Supported Carbonyl Complexes of Cobalt(I)
| Autor: | Travis J. Hebden, Louise M. Guard, D. Michael Heinekey, Donald E. Linn |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Pincer movement Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Cobalt Carbon monoxide |
| Zdroj: | Organometallics. 36:3104-3109 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.7b00434 |
| Popis: | A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of (tBuPOCOP)Co(CO) with H2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir. |
| Databáze: | OpenAIRE |
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