Reactivity of NO2 with Porous and Conductive Copper Azobispyridine Metallopolymers
| Autor: | Robert M. Waymouth, Shengkai Wang, Benjamin D. Matson, Adam H. Slavney, Hemamala I. Karunadasa, Mary Anne Manumpil, Naomi E. Clayman, Ritimuka Sarangi |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Chemistry Inorganic chemistry Infrared spectroscopy chemistry.chemical_element Disproportionation respiratory system Conductivity 010402 general chemistry complex mixtures 01 natural sciences Copper Redox 0104 chemical sciences body regions Inorganic Chemistry chemistry.chemical_compound Nitrogen dioxide Reactivity (chemistry) Physical and Theoretical Chemistry Porosity |
| Zdroj: | Inorganic Chemistry. 58:10856-10860 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.9b01190 |
| Popis: | We report the reactivity of copper azobispyridine (abpy) metallopolymers with nitrogen dioxide (NO2). The porous and conductive [Cu(abpy)]n mixed-valence metallopolymers undergo a redox reaction with NO2, resulting in the disproportionation of NO2 gas. Solid- and gas-phase vibrational spectroscopy and X-ray analysis of the reaction products of the NO2-dosed metallopolymer show evidence of nitrate ions and nitric oxide gas. Exposure to NO2 results in complete loss of porosity and a decrease in the room-temperature conductivity of the metallopolymer by four orders of magnitude with the loss of mixed-valence character. Notably, the porous and conductive [Cu(abpy)]n metallopolymers can be reformed by reducing the Cu-nitrate species. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|