Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex

Autor:	Matti Haukka, Vadim P. Boyarskiy, Konstantin V. Luzyanin, V. Yu. Kukushkin, Mikhail A. Kinzhalov
Rok vydání:	2013
Předmět:	Ligand Isocyanide Electrospray ionization Cationic polymerization Infrared spectroscopy chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy Photochemistry Metal chemistry.chemical_compound chemistry visual_art Polymer chemistry visual_art.visual_art_medium Palladium
Zdroj:	Russian Chemical Bulletin. 62:758-766
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-013-0103-4
Popis:	The reaction of cis-dichlorobis(2,6-xylylisocyanide)palladium(ii) with 2-aminopyrazine affords a binuclear palladium complex, in which one of the metal atoms is involved in the palladacyclic ligand. In the contrast, the coupling of isocyanide ligands in cis-dichlorobis-(2,6-xylylisocyanide)palladium(ii) with another C-amino aza-substituted heterocycle, viz.,4-acetyl-3-amino-5-methylpyrazole, gives a mononuclear cationic palladium diaminocarbene complex. Both compounds were characterized by elemental analysis, IR spectroscopy, 1H, 13C{1H}, DEPT90/DEPT135, and 1H,13C-HSQC/1H,13C-HMBC NMR spectroscopy, high-resolution electrospray ionization mass spectrometry, and X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::057e614d6c53698c7202641afa36f479 https://doi.org/10.1007/s11172-013-0103-4 Zobrazit plný text záznamu Full text from SpringerLink