Macrocyclic diphosphine ligands in asymmetric carbon-carbon bond-forming reactions
| Autor: | Michael Widhalm, Petra Wimmer, Gerd Klintschar |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
inorganic chemicals
Stereochemistry organic chemicals Organic Chemistry chemistry.chemical_element Biochemistry Catalysis Inorganic Chemistry Nickel chemistry Transition metal Asymmetric carbon Polymer chemistry health occupations polycyclic compounds Materials Chemistry heterocyclic compounds Physical and Theoretical Chemistry Chirality (chemistry) Carbon Palladium |
| Zdroj: | Journal of Organometallic Chemistry. 523:167-178 |
| ISSN: | 0022-328X |
| Popis: | Seven chiral macrocyclic ligands with potential O2P2 and N2P2 coordination sites owing their chirality from the incorporation of an axial-chiral binaphthyl unit were used as chiral auxiliaries in transition metal catalyzed carbon-carbon bond-forming reactions. Three model reactions were investigated, and enantioselectivities are discussed on the basis of accepted mechanistic pathways by using X-ray structural analyses. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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