An Environment Friendly Preparation of 3-Bromocamphor and Camphorquinone

Autor: Ashutosh V. Bedekar, Jayaraman Kannappan
Rok vydání: 2012
Předmět:
Zdroj: Journal of Chemical Research. 36:141-143
ISSN: 2047-6507
1747-5198
DOI: 10.3184/174751912x13295761942437
Popis: The bromination of camphor has been carried out on a multi-gram scale by a mixture of KBr and KBrO3 in the presence of acid or with HBr/NaBr - H+ and H2O2/oxone® as the oxidant. The 3-bromocamphor is then efficiently converted to camphorquinone by an improved oxidation protocol using DMSO and sodium carbonate of tetrabutyl ammonium iodide.
Databáze: OpenAIRE