An Environment Friendly Preparation of 3-Bromocamphor and Camphorquinone
Autor: | Ashutosh V. Bedekar, Jayaraman Kannappan |
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Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Journal of Chemical Research. 36:141-143 |
ISSN: | 2047-6507 1747-5198 |
DOI: | 10.3184/174751912x13295761942437 |
Popis: | The bromination of camphor has been carried out on a multi-gram scale by a mixture of KBr and KBrO3 in the presence of acid or with HBr/NaBr - H+ and H2O2/oxone® as the oxidant. The 3-bromocamphor is then efficiently converted to camphorquinone by an improved oxidation protocol using DMSO and sodium carbonate of tetrabutyl ammonium iodide. |
Databáze: | OpenAIRE |
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