Lupane triterpenoid glycosyl esters from leaves of Acanthopanax divaricatus
| Autor: | Masazumi Miyakoshi, Yoshiteru Ida, Sawako Mimoto, Yohko Satoh, Susumu Isoda, Katsuya Shirasuna, Junzo Shoji, Yasuaki Hirai |
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| Rok vydání: | 1997 |
| Předmět: |
chemistry.chemical_classification
Acanthopanax divaricatus biology Stereochemistry Saponin Glycoside Plant Science General Medicine Horticulture biology.organism_classification Biochemistry chemistry.chemical_compound chemistry Triterpene Molecule Araliaceae Glycosyl Molecular Biology Derivative (chemistry) |
| Zdroj: | Phytochemistry. 45:579-584 |
| ISSN: | 0031-9422 |
| DOI: | 10.1016/s0031-9422(97)00017-4 |
| Popis: | Further investigation of the leaves of Acanthopanax divaricatus gave two analogues of chiisanoside, which is a lupane triterpenoid oligoglycosyl ester. The structures were established as 28- O -α- l -rhamnopyranosyl(1 → 4)-β- d -glucopyranosyl(1 → 6)β- d -glucopyranosyl esters of 1β,11α-dihydroxy-3-oxo-lup-20(29)-en-28-oic acid and 1( R ),11α,22α-trihydroxy-3,4-seco-lupa-4(23),20(29)-diene-3,28-dioic acid 3,11α-lactone based on chemical and spectroscopic evidence. in biosynthetic terms, one is the precursor of chiisanoside and the other is an oxygenated derivative chiisanoside. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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